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A complete look at the dissociation dynamics of vinylfluoride at 157 nm
- Source :
- The Journal of Chemical Physics. 116:6982-6989
- Publication Year :
- 2002
- Publisher :
- AIP Publishing, 2002.
-
Abstract
- Photodissociation of vinylfluoride (H2CCFH) at 157 nm has been investigated using the photofragment translational spectroscopy technique. Five dissociation pathways have been clearly observed: H2CCF/HCCHF+H, HCCF+2H, HCCH+H+F, HCCH/H2CC:+HF, and HCCF/HFCC:+H2. Molecular HF elimination and the HCCH+H+F triple dissociation channel are found to be equally important, while other channels are all minor. The product kinetic energy distributions for all dissociation channels have been determined. Branching ratios for different channels have also been estimated.
Details
- ISSN :
- 10897690 and 00219606
- Volume :
- 116
- Database :
- OpenAIRE
- Journal :
- The Journal of Chemical Physics
- Accession number :
- edsair.doi...........29aca43614a543ae7fd6a288e89ce18e