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A Photochemical Approach to the Gelsemine Skeleton

Authors :
Clive S. Penkett
Anthony G. Avent
Paul W. Byrne
Source :
Organic Letters. 1:2073-2075
Publication Year :
1999
Publisher :
American Chemical Society (ACS), 1999.

Abstract

A silicon-tethered intramolecular meta photocycloaddition reaction was utilized to prepare a photoadduct, which was subsequently fragmented using m-CPBA to give a model for the skeleton of the alkaloid gelsemine.

Details

ISSN :
15237052 and 15237060
Volume :
1
Database :
OpenAIRE
Journal :
Organic Letters
Accession number :
edsair.doi...........2944855036c6c8abc06fdb16b6661664
Full Text :
https://doi.org/10.1021/ol991119j