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Changes in remanence, coercivity and domain state at low temperature in magnetite
- Source :
- Earth and Planetary Science Letters. 194:343-358
- Publication Year :
- 2002
- Publisher :
- Elsevier BV, 2002.
-
Abstract
- Submicron magnetite crystals with mean sizes of 0.037, 0.10 and 0.22 μm undergo major changes in hysteresis properties and domain states in crossing the Verwey transition ( T V ≈120 K). The 0.037 μm crystals are single-domain (SD) both in the cubic phase at room temperature T 0 and in the monoclinic phase below T V . The 0.10 and 0.22 μm crystals have a mixture of SD and two-domain (2D) states at room temperature T 0 , but mainly SD structures below T V , in agreement with micromagnetic calculations. Coercive force H c increases on cooling through T V , by a factor 3–5 in the submicron magnetites and 40 in a 1.3 mm single crystal, because of the high crystalline anisotropy and magnetostriction of monoclinic magnetite. As a result, domain walls and SD moments are so effectively pinned below T V that all remanence variations in warming or cooling are reversible. However, between ≈100 K and T 0 , remanence behavior is variable. Saturation remanence (SIRM) produced in monoclinic magnetite at 5 K drops by 70–100% in warming across T V , with minor recovery in cooling back through T V (ultimate levels at 5 K of 23–37% for the submicron crystals and 3% for the 1.3 mm crystal). In contrast, SIRM produced in the cubic phase at 300 K decreases 5–35% (submicron) or >95% (1.3 mm) during cooling from 300 to 120 K due to continuous re-equilibration of domain walls, but there is little further change in cooling through T V itself. However, the submicron magnetites lose a further 5–15% of their remanence when reheated through T V . These irreversible changes in cycling across T V , and the amounts of the changes, have potential value in determining submicron magnetite grain sizes. The irreversibility is mainly caused by 2D→SD transformations on cooling through T V , which preserve or enhance remanence, while SD→2D transformations on warming through T V cause remanence to demagnetize.
- Subjects :
- Magnetic domain
Analytical chemistry
Coercivity
chemistry.chemical_compound
Charge ordering
Geophysics
Nuclear magnetic resonance
chemistry
Space and Planetary Science
Geochemistry and Petrology
Remanence
Earth and Planetary Sciences (miscellaneous)
Single crystal
Saturation (magnetic)
Geology
Magnetite
Monoclinic crystal system
Subjects
Details
- ISSN :
- 0012821X
- Volume :
- 194
- Database :
- OpenAIRE
- Journal :
- Earth and Planetary Science Letters
- Accession number :
- edsair.doi...........2939d766ff7993434b81c7dbb5023417