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A new bipodal carboxy-bis(hydroxypyridinonate) ligand
- Source :
- Polyhedron. 21:2609-2616
- Publication Year :
- 2002
- Publisher :
- Elsevier BV, 2002.
-
Abstract
- A new tetradentate ligand having two 3-hydroxy-4-pyridinonate moieties and one carboxylate group appended to a cyclohexane backbone is reported, together with the corresponding bidentate hydroxypyridinonate pendant arm. The synthesis and characterization of these ligands, as well as their complexation properties towards the first transition series of metal ions M(II) (M=Cu, Ni, Zn) in aqueous solution, are described and discussed herein. The tetradentate ligand forms quite stable complexes with this series of metal ions and in solution, it is proved to be a much more effective chelator than the corresponding bidentate derivative. The stability constants of the complexes formed with this set of bivalent ions follow the Irving–Williams order Ni Zn. The carboxylic group has no interaction with the metal centre, thus remaining free for potential interaction with biological ligands (e.g. proteins).
- Subjects :
- Denticity
Aqueous solution
Ligand
Metal ions in aqueous solution
Inorganic chemistry
chemistry.chemical_element
Zinc
Inorganic Chemistry
Metal
chemistry.chemical_compound
chemistry
visual_art
Polymer chemistry
Materials Chemistry
visual_art.visual_art_medium
Chelation
Carboxylate
Physical and Theoretical Chemistry
Subjects
Details
- ISSN :
- 02775387
- Volume :
- 21
- Database :
- OpenAIRE
- Journal :
- Polyhedron
- Accession number :
- edsair.doi...........28b512ff08c70608b9e5baf61d14afe2