Effects of oxygen related thermal donors on the performance of silicon heterojunction solar cells

Absract The influence of oxygen-related thermal donors (TDs) on the performance of silicon heterojunction (SHJ) solar cells was explored experimentally in this paper. It is found that a certain number of thermal donors could do much harm to the performance of SHJ solar cells. The efficiency of SHJ solar cells is usually reduced by a value of ~ 1% absolute in the case of thermal donors with a concentration of nearly 1015 cm−3. The microwave photoconductance decay and Hall Effect studies have proved that the TDs can significantly reduce the carrier lifetime of n-type silicon substrate, but have no influence on the carrier mobility. Deep level transient spectroscopy (DLTS) measurements have further demonstrated that the TDs cause an energy level at Ec-0.13 eV with carrier capture cross-section of 10−15 cm2, which is responsible for the reduction of carrier lifetime and solar cell efficiency.