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NaIO4/LiBr-mediated aziridination of olefins using chloramine-T
- Source :
- Tetrahedron Letters. 51:6460-6462
- Publication Year :
- 2010
- Publisher :
- Elsevier BV, 2010.
-
Abstract
- A new milder protocol for aziridination of a variety of olefins has been described. The process employs catalytic amount of sodium metaperiodate (NaIO 4 ) as an oxidant and LiBr and chloramine-T as the bromine and nitrogen sources, respectively. Interestingly, the formation of aziridine products in all the cases studied takes place presumably through a process of 1,2-aminobromination of alkenes.
Details
- ISSN :
- 00404039
- Volume :
- 51
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi...........286729fb7c51f9538bf58d1821a36e97
- Full Text :
- https://doi.org/10.1016/j.tetlet.2010.10.005