Densification of high-strength B 4 C–TiB 2 composites fabricated by pulsed electric current sintering of TiC–B mixture

The densification and mechanical properties of B4C–TiB2 composites fabricated by reactive pulsed electric current sintering from a mixture of TiC and amorphous B powders were investigated. The excess of B was essential to remove the carbon produced by the reaction. The degassing process at 1900 °C before applying a 50 MPa external pressure greatly improved the densification of the composites. The B4C–41 vol% TiB2 composite obtained at the optimum condition had a high 3-point bending strength of 891 MPa, a Vickers hardness of 28 GPa and a fracture toughness of 4.4 MPa m1/2, respectively.