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Optical and structural investigation of dysprosium doped-Y2Te4O11
- Source :
- Journal of Luminescence. 173:11-18
- Publication Year :
- 2016
- Publisher :
- Elsevier BV, 2016.
-
Abstract
- In this paper, the optical properties of Y 2 Te 4 O 11 microcrystalline powders doped with Dy 3+ ions, ranging between 0.01 and 5.0 at%, are reported. The powders were successfully synthesized by the solid state reaction method. Absorption (300 K), excitation (300 K) and fluorescence spectra (at 11.6 and 300 K) as well as fluorescence decay curves recorded at room temperature are presented and analyzed in details. Oscillator strengths, phenomenological Ω λ ( λ =2, 4, 6) Judd-Ofelt parameters, radiative transition probabilities, branching ratios, the radiative lifetime of the 4 F 9/2 level as well as the stimulated emission cross-section for the 4 F 9/2 → 6 H 13/2 transition have been determined. The observed non-exponential decay nature and concentration quenching of the 4 F 9/2 emitting level of the Dy 3+ ion, have been attributed to cross-relaxation processes. The high value of the stimulated emission cross-section for the 4 F 9/2 → 6 H 13/2 transition at 576.6 nm, equal to 0.756×10 −20 cm 2 , indicates that Y 2 Te 4 O 11 activated by trivalent dysprosium ions is an attractive candidate for a solid-sate laser.
- Subjects :
- 010302 applied physics
Chemistry
Doping
Biophysics
Analytical chemistry
chemistry.chemical_element
02 engineering and technology
General Chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
01 natural sciences
Biochemistry
Fluorescence
Atomic and Molecular Physics, and Optics
Ion
0103 physical sciences
Radiative transfer
Dysprosium
Stimulated emission
0210 nano-technology
Luminescence
Excitation
Subjects
Details
- ISSN :
- 00222313
- Volume :
- 173
- Database :
- OpenAIRE
- Journal :
- Journal of Luminescence
- Accession number :
- edsair.doi...........27452d28b5bdeb0f6638fe1dd6583ddc