Proterozoic carbonate-hosted Morro Agudo sulfide Pb-Zn district, Brazil: Mineralogical and geochemical evidence of fluid mixing during the ore stage

The Proterozoic Vazante-Paracatu mineral belt hosts distinct styles of mineralization in carbonate rocks, including world-class hypogene silicate-zinc deposits in the south and sulfide Zn-Pb deposits in the north. This study focuses on the Morro Agudo District (Morro Agudo deposit and Bento Carmelo, Sucuri, and Morro do Capao occurrences). The genesis of the Morro Agudo sulfide deposit is controversial (i.e., syn-diagenetic or syn-orogenic), and little was known about the other occurrences. Ore is stratigraphically controlled within distinct dolomitic units of the Morro do Calcario and Lapa formations and structurally controlled at the Morro Agudo deposit along a NW normal fault system. Mineralization is characterized by multiple generations of sphalerite and galena, coeval with hydrothermal Fe-rich dolomite, pyrite, and quartz, which overprint micritic and sparitic dolomite and diagenetic pyrite. The mineralized zones comprises Cd and Hg within the high-grade Zn-Pb ore and Ag, As, Cu, Fe, In, Se, Sb, and Tl extending into the hydrothermal halos surrounding the orebodies. The sphalerite compositions encompass variable proportions of Zn (58.75-66.92 wt. %), Fe (0.15-5.03 wt. %), and Cd (0.18-0.94 wt. %) grouped in five populations based on Cd-Fe ratios and principal component analysis. Sphalerite from various generations and locations in the orebodies and occurrences do not show any specific signature, suggesting episodic contribution of multiple fluids with distinct Fe and Cd contents. The whole rock lithogeochemistry revealed similar trace element signatures for the orebodies of Morro Agudo deposit and surrounding occurrences indicating, despite the textural differences, that these orebodies formed from similar mineralizing fluids and processes, except for the Bento Carmelo occurrence. This study shows clear evidence that the mineralization at the Morro Agudo deposit, Sucuri and Morro do Capao occurrences is epigenetic, forming after the diagenesis of the host carbonate succession, and may have involved progressive mixing of multiple fluids with distinct compositions that interacted with sulfur reservoirs in the dolomitic rocks, similar to other MVT districts worldwide. The Morro Agudo district is one of the rare examples of Proterozoic MVT districts, and this study brings new insights to the exploration of this type of mineralization in similar basins.