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Comment on 'Linear and bent triatomic molecules are not qualitatively different!'

Authors :
T. Amano
Source :
Canadian Journal of Physics. 99:1114-1115
Publication Year :
2021
Publisher :
Canadian Science Publishing, 2021.

Abstract

Jensen (Can. J. Phys. 98, 506 (2020). doi: 10.1139/cjp-2019-0395 ) presents theoretical justification for the claim that linear triatomic molecules are necessarily observed to be bent. The basis of the assertion is that the expectation value of the supplement of the bending angle, [Formula: see text] used in Jensen’s paper, is calculated to be positive. In this comment, we examine the interpretation of the expectation values of [Formula: see text] in stationary states, and indicate that Jensen’s claim contradicts a basic principle of quantum mechanics that the energy and geometrical variables cannot have definite values at the same time.

Details

ISSN :
12086045, 00084204, and 20190395
Volume :
99
Database :
OpenAIRE
Journal :
Canadian Journal of Physics
Accession number :
edsair.doi...........267db4c62e3e108b49aea656ead82540
Full Text :
https://doi.org/10.1139/cjp-2021-0130