Separation and Photophysical Properties of the ΔΔ, ΛΛ, ΔΛ, and ΛΔ Stereoisomers of a Dinuclear Ruthenium(II) Complex

Authors :: Christine O'Connor
Claudio Villani
Wesley R. Browne
Johannes G. Vos
Source :: Inorganic Chemistry. 40:5461-5464
Publication Year :: 2001
Publisher :: American Chemical Society (ACS), 2001.
Abstract: The separation of the four stereoisomers of [(Ru(bpy)2)2(bpt)](PF6)3 (where bpy = 2,2‘-bipyridine, Hbpt = 3,5-bis(pyridin-2-yl)-1H-1,2,4-triazole) by semipreparative HPLC is reported. The emission properties of the isomers obtained have been studied as a function of the enantiomeric purity of the solvent.

Subjects :: Delta
Stereochemistry
Ligand
Chemistry
Energy transfer
chemistry.chemical_element
Lambda
Ruthenium
Inorganic Chemistry
Solvent
Crystallography
Electron transfer
Physical and Theoretical Chemistry
Enantiomer

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