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A high performance SnO2/C nanocomposite cathode for aluminum-ion batteries

Authors :
Rong Jin
Dongshan Zhou
Yuanxin Wan
Chao Teng
Linling Li
Tianyi Wang
Yong Wang
Peitao Ding
Rong Wang
Gi Xue
Xiaoliang Wang
Hongyan Lu
Source :
Journal of Materials Chemistry A. 7:7213-7220
Publication Year :
2019
Publisher :
Royal Society of Chemistry (RSC), 2019.

Abstract

Rechargeable aluminum-ion batteries have been researched extensively due to their attractive features, such as the abundant aluminum resources and high capacity resulting from the three-electron redox properties. Herein, a porous carbon supported SnO2 nanocomposite is reported as a cathode material for AIBs. The resultant cell exhibits a high discharge specific capacity of 370 mA h g−1 (with an initial value of 434 mA h g−1) at 50 mA g−1. In the cycling performance, the cell retains a stabilized discharge capacity of 72 mA h g−1 after 20 000 cycles with a coulombic efficiency of ∼100% under an ultrahigh current density of 2 A g−1. Owing to the well-defined nanostructure, side reactions and pulverization of active particles can be prevented. The results indicate that the SnO2/C nanocomposite is a favorable cathode material for AIBs and opens up a new opportunity for the design of high-performance AIBs.

Details

ISSN :
20507496 and 20507488
Volume :
7
Database :
OpenAIRE
Journal :
Journal of Materials Chemistry A
Accession number :
edsair.doi...........25d980fdd13b3c3affc463616b339b28
Full Text :
https://doi.org/10.1039/c8ta11132d