Back to Search Start Over

Advanced anti-corrosion coatings prepared from α-zirconium phosphate/polyurethane nanocomposites

Authors :
Tsao-Cheng Huang
Mei-Hui Tsai
Yi-Hsiu Chung
Chen-En Li
Guan-Hui Lai
Peng-Yun Wan
Meng-Hung Lin
Source :
RSC Advances. 7:9908-9913
Publication Year :
2017
Publisher :
Royal Society of Chemistry (RSC), 2017.

Abstract

This paper presents the first successful application of α-zirconium phosphate/polyurethane (ZrP/PU) nanocomposites for corrosion protection. ZrP nanoplatelets were synthesized using a reflux method and modified with a polyetheramine surfactant (Jeffamine M1000) to form organic ZrP nanoplatelets. ZrP/PU nanocomposite films were based on PU and ZrP with different ZrP contents from 0.5–5 wt%. To probe the internal morphology of ZrP/PU nanocomposites, their cross-sections were examined by scanning and transmission electron microscopy. The results reveal that ZrP dispersed very well in PU films and that no substantial agglomeration occurred. Well-dispersed ZrP nanoplatelets in a PU matrix could effectively enhance the moisture barrier properties of ZrP/PU films. The water vapor transmission rate was significantly reduced to 84 g m−2 per day for ZrP/PU films compared to 194 g m−2 per day for pure PU films. Using a series of electrochemical measurements of corrosion potential (Ecorr), polarization resistance (Rp), corrosion current (Icorr), and electrochemical impedance spectroscopy, ZrP/PU coatings on cold-rolled steel electrodes were also found to exhibit enhanced corrosion protection properties compared to pure PU coatings.

Details

ISSN :
20462069
Volume :
7
Database :
OpenAIRE
Journal :
RSC Advances
Accession number :
edsair.doi...........256fdeb2d8dfe1f2bcf1cae0234e111b