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Homolytic allylation of vinyl iodides with allylstananes
- Source :
- Tetrahedron Letters. 40:8841-8844
- Publication Year :
- 1999
- Publisher :
- Elsevier BV, 1999.
-
Abstract
- In the presence of AIBN or Et3B, a variety of vinyl iodides reacted with allylstannanes bearing an electron-withdrawing group at the β-position to afford 1,4-dienes in moderate to good yields. The allylation showed high stereoselectivity when the α-substituent of the iodides was a phenyl group, or the β-substituent was a bulky group.
Details
- ISSN :
- 00404039
- Volume :
- 40
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi...........23a45c9b0f0c813183b04a8e34bc8984