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Phase diagram, chemical stability and physical properties of the solid-solution Ba4Nb2−Ta O9
- Source :
- Journal of Solid State Chemistry. 184:2648-2654
- Publication Year :
- 2011
- Publisher :
- Elsevier BV, 2011.
-
Abstract
- Through the construction of the Ba4Nb2−xTaxO9 phase diagram, it was discovered that the unique high-temperature γ phase is a thermodynamic intermediate between the low-temperature α phase (Sr4Ru2O9-type) and a 6H-perovskite. Refined site occupancies for the γ phase across the Ba4Nb2−xTaxO9 solid-solution indicate that Nb preferentially occupies the tetrahedral sites over the octahedral sites in the structure. When annealed in a CO2-rich atmosphere, all of the phases studied absorb large amounts of CO2 at high temperatures between ∼ 700 and 1300 K. In situ controlled-atmosphere diffraction studies show that this behaviour is linked to the formation of BaCO3 on the surface of the material, accompanied by a Ba5(Nb,Ta)4O15 impurity phase. In situ diffraction in humid atmospheres also confirms that these materials hydrate below ∼ 1273 K , and that this plays a critical role in the various reconstructive phase transitions as well as giving rise to proton conduction.
- Subjects :
- Phase transition
Materials science
Inorganic chemistry
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
Condensed Matter Physics
01 natural sciences
0104 chemical sciences
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Crystallography
13. Climate action
Impurity
Phase (matter)
Materials Chemistry
Ceramics and Composites
Chemical stability
Physical and Theoretical Chemistry
0210 nano-technology
Hydrate
Phase diagram
Perovskite (structure)
Solid solution
Subjects
Details
- ISSN :
- 00224596
- Volume :
- 184
- Database :
- OpenAIRE
- Journal :
- Journal of Solid State Chemistry
- Accession number :
- edsair.doi...........21e1d400fcf24ed2621674755732336d