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Physical Organic Chemistry of Transition Metal Complexes. 31. Nucleophilic Attachment of the Malononitrile Anion to Fischer Carbene Complexes
- Source :
- Organometallics. 23:6134-6139
- Publication Year :
- 2004
- Publisher :
- American Chemical Society (ACS), 2004.
-
Abstract
- Rate constants for the attachment of CH(CN)2- to Fischer carbene complexes of the type (CO)5MC(XR)C6H4Z with M = Cr, W and XR = OMe, OEt, SMe in 50% MeCN−50% water (v/v) at 25 °C are reported. The ...
Details
- ISSN :
- 15206041 and 02767333
- Volume :
- 23
- Database :
- OpenAIRE
- Journal :
- Organometallics
- Accession number :
- edsair.doi...........20ec9566ecc11b8c8ba6bb56a6d6b99d
- Full Text :
- https://doi.org/10.1021/om0401051