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A redox-active inorganic crown ether based on a polyoxometalate capsule

Authors :
Nanako Tamai
Naoki Ogiwara
Eri Hayashi
Keigo Kamata
Toshiyuki Misawa
Takeru Ito
Tatsuhiro Kojima
Mireia Segado
Enric Petrus
Carles Bo
Sayaka Uchida
Source :
Chemical Science. 14:5453-5459
Publication Year :
2023
Publisher :
Royal Society of Chemistry (RSC), 2023.

Abstract

The POM capsule functions as a redox-active inorganic crown ether. Specifically, Cs+ ions are captured in the crown-ether-like pores {Mo3Fe3O6}, which exist on the surface of the capsule, and electrons are stored in the Mo atoms of the capsule.

Subjects

Subjects :
General Chemistry

Details

ISSN :
20416539 and 20416520
Volume :
14
Database :
OpenAIRE
Journal :
Chemical Science
Accession number :
edsair.doi...........20dbe1875663313ae0ee49d5fc0466a4