Mesomorphic properties of symmetrical and asymmetrical triphenylene homologues possessing fluoroalkylated side chains

Two types of homologues (symmetrical and asymmetrical in rotational symmetry) of novel triphenylene compounds possessing fluoroalkyl and alkyl side chains were synthesized via an alternative method. X‐ray diffraction and DSC measurements showed that these homologues are thermotropic liquid crystals with a hexagonal columnar (Colh) mesophase. The phase transition temperatures (Colh–Iso) for both symmetrical and asymmetrical fluoroalkyloxytriphenylenes increase to about 180°C, and are independent of fluoromethylene chain and the rotational symmetry of chemical structure. The Colh phase of symmetrical and asymmetrical fluoroalkyloxytriphenylenes possessing three fluoroalkyl side chains are more stable than fluoroalkyloxytriphenylenes possessing six fluoroalkyl side chains and alkyloxytriphenylenes. The X‐ray diffraction patterns for symmetrical and asymmetrical fluoroalkyloxytriphenylenes, fluoroalkyloxytriphenylenes and alkyloxytriphenylenes in the wide‐angle region are compared.