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A straightforward and versatile protocol for the direct conversion of benzylic azides to ketones and aldehydes

Authors :
Eduardo Díaz-Torres
Marco A. Morales-Reza
Carlos González-Romero
Davir González-Calderón
Aydeé Fuentes-Benítes
Source :
RSC Advances. 6:83547-83550
Publication Year :
2016
Publisher :
Royal Society of Chemistry (RSC), 2016.

Abstract

We report that the benzyl azido group is directly converted to carbonyls in good yields through a rapid hydrolysis (basic conditions) of benzylideneamides generated readily/efficiently in situ under a very simple procedure involving conventional reagents.

Details

ISSN :
20462069
Volume :
6
Database :
OpenAIRE
Journal :
RSC Advances
Accession number :
edsair.doi...........1f74a2ef5c55aa66f1c0de7dc7651b48
Full Text :
https://doi.org/10.1039/c6ra13088g