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Development of a Scalable Negishi Cross-Coupling Process for the Preparation of 2-Chloro-5-(1-(tetrahydro-2H-pyran-2-yl)-1H-pyrazol-5-yl)aniline

Authors :
James Chadwick
Candice L. Joe
Jeffrey Nye
Albert J. DelMonte
Sha Lou
Bahar Inankur
Neil A. Strotman
Source :
Organic Process Research & Development. 25:434-441
Publication Year :
2020
Publisher :
American Chemical Society (ACS), 2020.

Abstract

A scalable synthesis of 2-chloro-5-(1-(tetrahydro-2H-pyran-2-yl)-1H-pyrazol-5-yl)aniline (1), a key intermediate in the synthesis of an immuno-oncology asset, is described. A Negishi cross-coupling...

Details

ISSN :
1520586X and 10836160
Volume :
25
Database :
OpenAIRE
Journal :
Organic Process Research & Development
Accession number :
edsair.doi...........1f13d45db405b7d6237f0ec7178f1293
Full Text :
https://doi.org/10.1021/acs.oprd.0c00414