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Reaction of Chiral Secondary Amines with [(η5-C5Me5)MCl2]2 (M = Rh(III), Ir(III)): Cyclometalation with or without Dehydrogenation
- Source :
- Organometallics. 30:1168-1174
- Publication Year :
- 2011
- Publisher :
- American Chemical Society (ACS), 2011.
-
Abstract
- The reaction of (2R,5R)-2,5-diphenylpyrrolidine (L1) with [(η5-C5Me5)MCl2]2 (M = Rh, Ir) in acetonitrile in the presence of KPF6 and NaOH at room temperature led to mixtures of two products, [(η5-C...
Details
- ISSN :
- 15206041 and 02767333
- Volume :
- 30
- Database :
- OpenAIRE
- Journal :
- Organometallics
- Accession number :
- edsair.doi...........1e2ffacf6a0121450c2dd0c5f35b584d
- Full Text :
- https://doi.org/10.1021/om101148v