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Double-shell SnO2/CeO2:Yb,Er hollow nanospheres as an assistant layer that suppresses charge recombination in dye-sensitized solar cells
- Source :
- New Journal of Chemistry. 42:14453-14458
- Publication Year :
- 2018
- Publisher :
- Royal Society of Chemistry (RSC), 2018.
-
Abstract
- Double-shell SnO2/CeO2:Yb,Er hollow nanospheres (HNSs) are prepared using SiO2 as a template. Firstly, CeO2:Yb,Er nanoparticles (NPs) were coated on the surface of SiO2 to generate core–shell SiO2@CeO2:Yb,Er nanospheres. Then the SiO2 cores were removed accompanied by SnO2 deposition to form heterogeneous double-shell SnO2/CeO2:Yb,Er HNSs during a hydrothermal process. It can be seen from the structure analysis that the deposition of the SnO2 shell as the framework supports the CeO2:Yb,Er shell. When SnO2/CeO2:Yb,Er HNSs act as an assistant layer in dye-sensitized solar cells (DSSCs), the photoelectric conversion efficiency (PCE) is enhanced to 8.66%. Open-circuit voltage decay confirms that the lifetime of photogenerated electrons in the cells is prolonged. Double-shell SnO2/CeO2:Yb,Er HNSs might efficiently suppress the recombination of photoproduced electrons–holes, extend the electron lifetime, and further improve the photoelectric conversion performance of DSSCs.
- Subjects :
- Chemistry
Shell (structure)
Nanoparticle
02 engineering and technology
General Chemistry
Electron
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Catalysis
Hydrothermal circulation
0104 chemical sciences
Dye-sensitized solar cell
Chemical engineering
Materials Chemistry
0210 nano-technology
Layer (electronics)
Deposition (law)
Recombination
Subjects
Details
- ISSN :
- 13699261 and 11440546
- Volume :
- 42
- Database :
- OpenAIRE
- Journal :
- New Journal of Chemistry
- Accession number :
- edsair.doi...........1e1f87abe3e2d57405d933183d89f9d2