Anion-templated formation of a unique inorganic ‘super-adamantoid’ cage [Ag6(triphos)4(O3SCF3)4]2+ [triphos = (PPh2CH2)3CMe]

Authors :: Andrew J. P. White
Stuart L. James
David J. Williams
D. Michael P. Mingos
Source :: Chemical Communications. :2323-2324
Publication Year :: 1998
Publisher :: Royal Society of Chemistry (RSC), 1998.
Abstract: In the presence of templating anions, 2:3 molar mixtures of triphos and silver(I) cations unexpectedly give novel hexanuclear cages, which result from an unusual ‘endo-methyl’ geometry of the triphos ligands.

Subjects :: chemistry.chemical_compound
Crystallography
chemistry
Materials Chemistry
Metals and Alloys
Ceramics and Composites
General Chemistry
Cage
Catalysis
Triphos
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Ion

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