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ChemInform Abstract: Photochemical C-C Bond Cleavage of 1,2-Diarylcyclopropanes Bearing an Acetylphenyl Group. Generation and Observation of Triplet 1,3-Biradicals

Authors :
Kazuhiko Mizuno
Nobuyuki Ichinose
Yoshio Otsuji
Anna M. Helms
Richard A. Caldwell
Source :
ChemInform. 29
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

The photochemical properties of 1,2-diarylcyclopropanes bearing an acetylphenyl group were studied by product analysis and laser flash photolysis. All cyclopropanes showed efficient cis−trans photoisomerization followed by inefficient isomerization to 1,3-diarylpropenes. All the products were unquenched by the addition of triplet quencher, 2-methyl-1,3-butadiene (ET ≃ 60 kcal mol-1), whereas molecular dioxygen gave oxygenated products. Triplet 1,3-biradicals generated from a short-lived acetophenone-like triplet (≲1 ns) were observed as intermediates in these reactions through nanosecond laser flash photolysis. Polar substituent effects on the lifetime of the 1,3-biradicals were small, except for a heavy atom effect in the case of Br. Spin−orbit coupling calculations on model 1,3-biradicals show a negligible effect on polar substituent and thus predict a negligible effect on the intersystem crossing rate. Conjugated biradicals in general now seem unlikely to show the “ionic character effect” on intersyste...

Details

ISSN :
15222667 and 09317597
Volume :
29
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........1d1b7825cfccb1989ca4443e132eadd1