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Detection of the tetrahedral reaction intermediate of the reaction of acetyl chloride with ethanol in microdroplets via laser desorption/ionization tandem mass spectrometry

Authors :
Victoria M. Boulos
Jeremy Marcum
Hao Ran Lei
Yuyang Zhang
Hannah E. Natvig
Benjamin Updike
Timothée L. Pourpoint
Hilkka I. Kenttämaa
Source :
Physical Chemistry Chemical Physics. 24:24690-24694
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

The controversial tetrahedral intermediate of the reaction between acetyl chloride and ethanol was detected using novel methodology. The results demonstrate that the reaction proceeds via an addition/elimination mechanism.

Details

ISSN :
14639084 and 14639076
Volume :
24
Database :
OpenAIRE
Journal :
Physical Chemistry Chemical Physics
Accession number :
edsair.doi...........1b8d1f20dc5b631016c210d8a62e5583