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The first enantiospecific synthesis of (+)-10,11-epoxythapsan-10-ol: revision of the absolute stereochemistry of thapsanes
- Source :
- Tetrahedron Letters. 43:5261-5264
- Publication Year :
- 2002
- Publisher :
- Elsevier BV, 2002.
-
Abstract
- The first enantiospecific synthesis of (+)-cis,anti,cis-1,8,12,12-tetramethyl-4-oxatricyclo[6.4.0.02,6]dodecan-3-ol (+)-1g, an enantiomer of natural thapsane isolated from Thapsia villosa var minor, is accomplished starting from (R)-carvone, which revises the absolute stereochemistry of natural thapsanes.
Details
- ISSN :
- 00404039
- Volume :
- 43
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi...........1b1534f220a006e0fcf6911352fb7694