ChemInform Abstract: Palladium-Mediated Cyclization of 1,5-Hexadien-3-ols to 1-Methyl-1,3- cyclopentadienes

Authors :: T. Zair
Christiane Santelli-Rouvier
Maurice Santelli
Source :: ChemInform. 24
Publication Year :: 2010
Publisher :: Wiley, 2010.
Abstract: Treatment of 1,5-hexadien-3-ols in acetic acid by Pd(0) [Pd(PPh 3 ) 4 ] led to 1-methyl-1,3-cyclopentadienes. Cyclization is improved by the presence of catalytic amount of trifluoroacetic acid. Mechanism is discussed from the observed results with deuterated alcohols.

Subjects :: Acetic acid
chemistry.chemical_compound
Deuterium
Chemistry
Trifluoroacetic acid
chemistry.chemical_element
General Medicine
Medicinal chemistry
Catalysis
Palladium

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