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Microporous carbon derived from polyaniline base as anode material for lithium ion secondary battery

Authors :
Zhengzheng Huang
Enhui Liu
Yingying Tian
Jingjing Yang
Xiaoxia Xiang
Chengyi Xiao
Zhaohui Mao
Haijie Shen
Source :
Materials Research Bulletin. 46:1266-1271
Publication Year :
2011
Publisher :
Elsevier BV, 2011.

Abstract

Microporous carbon with large surface area was prepared from polyaniline base using K2CO3 as an activating agent. The physicochemical properties of the carbon were characterized by scanning electron microscope, X-ray diffraction, Brunauer–Emmett–Teller, elemental analyses and X-ray photoelectron spectroscopy measurement. The electrochemical properties of the microporous carbon as anode material in lithium ion secondary battery were evaluated. The first discharge capacity of the microporous carbon was 1108 mAh g−1, whose first charge capacity was 624 mAh g−1, with a coulombic efficiency of 56.3%. After 20 cycling tests, the microporous carbon retains a reversible capacity of 603 mAh g−1 at a current density of 100 mA g−1. These results clearly demonstrated the potential role of microporous carbon as anode for high capacity lithium ion secondary battery.

Details

ISSN :
00255408
Volume :
46
Database :
OpenAIRE
Journal :
Materials Research Bulletin
Accession number :
edsair.doi...........194927e31da4ab55806cdec86cb18faa
Full Text :
https://doi.org/10.1016/j.materresbull.2011.03.032