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Synthesis and reduction of α-amino ketones derived from leucine
- Source :
- J. Chem. Soc., Perkin Trans. 1. :1895-1899
- Publication Year :
- 1986
- Publisher :
- Royal Society of Chemistry (RSC), 1986.
-
Abstract
- New α-amino ketones (5) derived from leucine have been synthesized by reaction of organometallics on N-methoxy-N-methylamide (4). The stereoselectivity of reduction of the α-amino ketones (5) was studied. The stereochemistry of the resulting α-amino alcohols (6) was established by transforming them into the oxazolidinones (8) by means of a new procedure.
Details
- ISSN :
- 13645463 and 0300922X
- Database :
- OpenAIRE
- Journal :
- J. Chem. Soc., Perkin Trans. 1
- Accession number :
- edsair.doi...........18e8146d31f24666eec9a4104e29ab30