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Synthesis of optically active methylmenthoxychlorosilanes and menthyl esters of methylchlorosilylpropionic and methylchlorosilylisobutyric acids
- Source :
- Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 16:1432-1435
- Publication Year :
- 1967
- Publisher :
- Springer Science and Business Media LLC, 1967.
-
Abstract
- 1. The reaction of methylhydrochlorosilanes with the menthyl esters of acrylic and methacrylic acid gave seven new optically active menthyl esters of chlorosilylpropionic and chlorosilylisobutyric acid. The mono- and dimenthoxychloromethylsilanes were isolated when methyltrichlorosilane was etherified withl-menthol. 2. All of the obtained compounds have a negative rotation and give smooth negative rotation dispersion curves, which are satisfactorily described by the Drude equation in the wavelength range 302–612 mμ.
Details
- ISSN :
- 15739171 and 05685230
- Volume :
- 16
- Database :
- OpenAIRE
- Journal :
- Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
- Accession number :
- edsair.doi...........18bd1f51410c9211f5df022b2e04cf11