Optimization of random silica-polymethylpentene (TPX) radiative coolers towards substantial cooling capacity

In the context of global warming, radiative coolers with high solar reflectance and strong emissivity in the atmospheric window can cool the substrate as well as the ambient air. Silica at its nano or micro-scale being randomly dispersed into a uniform transparent polymer can form scalable radiative coolers for large-scale application. Promising cooling performance has been reported for silica-polymers compared with conventional cooling materials, but their performance can be largely influenced by various fabrication parameters. So far, how fabrication parameters influence the emissivity and the cooling performance has not been experimentally demonstrated and the cooling capacity of silica-polymers reported was not substantial compared to other superior radiative coolers. In this work, random silica-polymer has been optimized experimentally. Lab measurement and experimental testing of six fabricated silica-polymers under subtropical and desert climates indicated that due to the complexity of the thermo-radiative balance, high emissivity and strong selectivity are both indispensable in the production of high cooling power. If combined with superior reflectors with higher solar reflectance and especially the emissivity in 8–13 μm enhancing the heat dissipation ability, substantial cooling capacity can be achieved: under the harsh desert climate with average peak solar radiation over 1100 Wm-2, the combination presented sub-ambient temperature of maximum 4.7 °C when air temperature reached its peak and the maximum daytime and night-time sub-ambient temperatures were 12.5 °C and 15.9 °C respectively.