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Responsive electrolytes that inhibit electrochemical energy conversion at elevated temperatures
- Source :
- Journal of Materials Chemistry A. 3:4026-4034
- Publication Year :
- 2015
- Publisher :
- Royal Society of Chemistry (RSC), 2015.
-
Abstract
- Energy storage has emerged as a critical challenge due to the increasing demand to utilize energy from intermittent, renewable resources. Furthermore, growing interest in decreasing our dependence on petroleum necessitates the development of safe and efficient energy storage for transportation. Li-ion batteries have emerged as the premier candidate to meet these demands; however, such systems are limited by thermal hazards (runaway reactions, fires, explosions), which become increasingly dangerous in large-format batteries. We have developed an electrolyte system comprising poly(ethylene oxide), an ionic liquid and lithium salt that exhibits an intrinsic mechanism for inhibiting device operation when the temperature increases beyond a given threshold, which is attributed to polymer–ionic liquid phase separation. In the following article, we describe how the thermally activated phase separation causes a decrease in ion conductivity, thereby affecting the concentration of ions at the electrode, in addition to an increase in charge transfer resistance from the formation of a polymer coating on the porous electrode. Such mixtures provide a transformative approach to regulating electrochemical processes, which is necessary to achieve inherently safe operation of large format Li-ion batteries.
- Subjects :
- Materials science
Renewable Energy, Sustainability and the Environment
chemistry.chemical_element
Nanotechnology
General Chemistry
Electrolyte
Conductivity
Electrochemistry
Electrochemical energy conversion
Energy storage
chemistry.chemical_compound
chemistry
Electrode
Ionic liquid
General Materials Science
Lithium
Subjects
Details
- ISSN :
- 20507496 and 20507488
- Volume :
- 3
- Database :
- OpenAIRE
- Journal :
- Journal of Materials Chemistry A
- Accession number :
- edsair.doi...........18924591bc08380732b853616576d7c1