A New Evidence for the Presence of a Spiroindolenium Species in the Pictet-Spengler Reaction

Authors :: Masako Nakagawa
Koreharu Ogata
Tohru Hino
Tomohiko Kawate
Source :: HETEROCYCLES. 33:801
Publication Year :: 1992
Publisher :: The Japan Institute of Heterocyclic Chemistry, 1992.
Abstract: The Pictet-Spengler reaction of the imine (9) with chloro (-)-diisopinocamphenylborane yielded optically spiroindolines (14) and (15), providing a new evidence for the presence of a spiroindolenium intermediate

Subjects :: Pharmacology
Pictet–Spengler reaction
Bicyclic molecule
Stereochemistry
Organic Chemistry
Imine
Reaction intermediate
Crystal structure
Analytical Chemistry
chemistry.chemical_compound
chemistry
Polymer chemistry
X-ray crystallography
Molecule

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