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Studies on Organo Sulfur Compounds. VI. The Reaction of S-Methyl-O-α-acetylenyl Xanthates and Metal Xanthates
- Source :
- Chemical and Pharmaceutical Bulletin. 20:2302-2307
- Publication Year :
- 1972
- Publisher :
- Pharmaceutical Society of Japan, 1972.
-
Abstract
- Dimethyl trithiocarbonate (4), which was formed as one of by-products in the preparation of α-acetylenyl xanthate (3), was obtained by treating 2-propynyl xanthate (10) or 3-phenyl-2-propynyl xanthate (18) with potassium xanthate (17). The reaction pathway for the formation of 4 from 18 was studied in detail, and the mechanism of the formation of dimethyl trithiocarbonate (4) and other by-products were consequently clarified.
Details
- ISSN :
- 13475223 and 00092363
- Volume :
- 20
- Database :
- OpenAIRE
- Journal :
- Chemical and Pharmaceutical Bulletin
- Accession number :
- edsair.doi...........1845707b0509e4f8a0c94c4dee0601bf