Synergistic effects of frothers, collector and salt on bubble stability

This work investigates synergistic and antagonistic effects of flotation reagents and salt on the air–liquid interface and stability of air bubbles under quasi-static conditions. Frothers of different families (aliphatic alcohol, polypropylene glycol and propylene glycol methyl ether), potassium amyl xanthate (PAX), a common collector used in the flotation of sulphide minerals, and sodium chloride (NaCl) were employed in the study. Adsorption of frother and collector molecules from individual and mixed solutions was studied through surface tension and Quartz Crystal Microbalance with Dissipation (QCM–D) measurements, while bubble stability was examined by the coalescence time of the bubble pairs in these solutions. The results show that NaCl enhanced the adsorption of frothers, while PAX's impact on the adsorption of the frother was found to be rather insignificant compared to the salt. The bubble coalescence time measurements, however, pointed to a significant synergistic effect between PAX and two frothers i.e., Methyl Iso Butyl Carbinol (MIBC) and Di Propylene Glycol (DPG) as reflected in the improvement of bubble stability. In the ternary solution systems (frother/NaCl/PAX), the concentration of salt in the MIBC mixture solution was found to have an opposite impact on the bubble lifetime in the DPG and DPM solutions. For instance, bubble lifetime increased with higher NaCl concentrations added to the DPG and DPM solutions, whereas it decreased in the MIBC solutions.