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Substituent effects on the amination of racemic allyl carbonates using commercially available chiral rhodium catalysts
- Source :
- Tetrahedron Letters. 54:5795-5798
- Publication Year :
- 2013
- Publisher :
- Elsevier BV, 2013.
-
Abstract
- In the presence of commercially available chiral rhodium catalysts, a competitive benzylamination of racemic allyl carbonates, substituted with p-X-Ph groups, shows that the reaction proceeds faster with substituents (X) that are more electron-withdrawing. Mechanistic implications of these results are discussed.
Details
- ISSN :
- 00404039
- Volume :
- 54
- Database :
- OpenAIRE
- Journal :
- Tetrahedron Letters
- Accession number :
- edsair.doi...........16e96db7187281688f54fc7137e3002f