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Desymmetrization of disubstituted aromatic crown ethersviaintramolecular Cannizzaro reactions
- Source :
- New Journal of Chemistry. 43:16801-16805
- Publication Year :
- 2019
- Publisher :
- Royal Society of Chemistry (RSC), 2019.
-
Abstract
- Ba++templated Cannizzaro reactions convert symmetrical aromatic crown ether dialdehydes of various types [dibenzo and bis(meta-phenylene)] and sizes (20–32 atom rings) to acid–alcohol functionalized crown ethers in 70–98% yields.
- Subjects :
- chemistry.chemical_classification
Chemistry
Crown (botany)
Atom (order theory)
02 engineering and technology
General Chemistry
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Desymmetrization
Catalysis
0104 chemical sciences
Metal
visual_art
Intramolecular force
Polymer chemistry
Materials Chemistry
Cannizzaro reaction
visual_art.visual_art_medium
0210 nano-technology
Crown ether
Subjects
Details
- ISSN :
- 13699261 and 11440546
- Volume :
- 43
- Database :
- OpenAIRE
- Journal :
- New Journal of Chemistry
- Accession number :
- edsair.doi...........16bef4788fa581703588293262614e69
- Full Text :
- https://doi.org/10.1039/c9nj04679h