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Sterically Protected Dipotassium Germanedithiolate

Authors :
Tsuyoshi Matsumoto
Kazuyuki Tatsumi
Source :
Chemistry Letters. 30:964-965
Publication Year :
2001
Publisher :
The Chemical Society of Japan, 2001.

Abstract

The germanedithiols Dmp(Ar)Ge(SH)2 [Dmp=2,6-dimesitylphenyl; Ar = Dep (2,6-diethylphenyl) 1a, Tip (2,4,6-triisopropylphenyl) 1b] were synthesized by the reduction of hexathiagermepanes Dmp(Ar)GeS6 and tetrathiagermolanes Dmp(Ar)GeS4 with NaBH4. The treatment of 1awith 2 equiv of potassium hydride afforded the dipotassium germanedithiolate 2.

Subjects

Subjects :
Steric effects
chemistry.chemical_compound
chemistry
Potassium hydride
Stereochemistry
General Chemistry
Medicinal chemistry

Details

ISSN :
13480715 and 03667022
Volume :
30
Database :
OpenAIRE
Journal :
Chemistry Letters
Accession number :
edsair.doi...........168310690ac9f5e868f4476e9a699f42
Full Text :
https://doi.org/10.1246/cl.2001.964
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