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Non-Oxidative Conversion of 1,2-Dichloroethane in a Non-Thermal Plasma and Characterisation of the Polymer Formed

Authors :
John C. Mackie
Scott Molloy
Vaibhav Gaikwad
Bogdan Z. Dlugogorski
Eric M. Kennedy
Sazal Kundu
Clovia I. Holdsworth
Source :
Plasma Processes and Polymers. 10:141-149
Publication Year :
2012
Publisher :
Wiley, 2012.

Abstract

This paper focuses on the conversion of 1,2-dichloroethane (EDC) using non-thermal plasma under reaction conditions that can decompose EDC and yield a value-added product. A cylindrical double dielectric barrier discharge system has been used to generate non-thermal plasma and quartz has been used as a dielectric. Our findings show that under non-oxidative reaction conditions employed in this study, vinyl chloride, a commercially important compound, is the major gas phase product produced. This paper also encompasses a preliminary characterisation of polymer during the reaction. Possible mechanisms for gaseous product formation and polymerisation are presented.

Details

ISSN :
16128850
Volume :
10
Database :
OpenAIRE
Journal :
Plasma Processes and Polymers
Accession number :
edsair.doi...........1652708e6530abb22a93a4c93899f751
Full Text :
https://doi.org/10.1002/ppap.201200045