New approach to filled polymers

Mechanopolymerization of pentabromobenzyl (mono)acrylate (PBB-MA) on the surface of inorganic fillers Mg(OH)2 and CaCO3 was studied. The role of activated surface of fillers was investigated using DSC and FTIR. The influence of milling time and of the filler chemical content on polymerization starting temperature and polymerization enthalpy was studied using DSC. It was shown that an increase of the filler concentration leads to a higher maximum conversion degree. The correlation between conversion kinetics and polymerization enthalpy of the material notpolymerized during milling was shown.