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New Method to Enhance the ortho-para H2 Conversion by using Dynamical Quantum Filtering Effect and Steric Effect
- Source :
- SHINKU. 45:448-452
- Publication Year :
- 2002
- Publisher :
- The Vacuum Society of Japan, 2002.
-
Abstract
- We introduce a new method to enhance the orthohydrogen-parahydrogen (o-p H2) conversion yield /rate of a H2 interacting with a solid surface. This method consists of two steps. The first step involves the dynamical quantum filtering (DQF) process, and the second step relies on the steric effect on o-p H2 conversion. The purpose of the DQF process is to align the rotation of free rotating o-H2 such that we have only H2 in helicopter-like rotational states or H2 in cartwheel-like rotational states. In the second process, we bring these aligned o-H2 close to a catalyst surface (e.g., metal oxide surface). Based on the steric effect, o-H2 that has a cartwheel-like rotation will be converted to p-H2 with high rate.
- Subjects :
- Steric effects
Surface (mathematics)
Quantum filtering
Oxide
Condensed Matter Physics
Surfaces, Coatings and Films
Catalysis
Metal
chemistry.chemical_compound
chemistry
Chemical physics
visual_art
Yield (chemistry)
visual_art.visual_art_medium
Electrical and Electronic Engineering
Rotation (mathematics)
Subjects
Details
- ISSN :
- 18809413 and 05598516
- Volume :
- 45
- Database :
- OpenAIRE
- Journal :
- SHINKU
- Accession number :
- edsair.doi...........15c49808321401b22a57e83cdf071f45