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Flotator Oxal as the plasticizer for suspension PVC

Authors :
I Oscar Koifman
A Julia Rodicheva
P Irina Trifonova
A Vladimir Burmistrov
E Anna Sheveleva
Source :
Journal of the Serbian Chemical Society. 87:355-362
Publication Year :
2022
Publisher :
National Library of Serbia, 2022.

Abstract

The flotator Oxal, mixture of dioxane ethers and alcohols as well as 1, 2 and 3 atomic alcohols, has been studied as a plasticizer for suspension PVC in comparison with the well-known dibutyl phthalate (DBP) and di-(2-ethylhexyl) phthalate (DOP). The rheological parameters and gelation ability of plasticizers were determined, the values of the storage modulus and tangent of mechanical loss angle in the glassy and rubbery states were measured by the DMA method, and the glass transition temperatures were determined. The deformation-strength properties and rigidity of polymer films were tested before and after light-thermal aging. Oxal was shown to reveal a fairly low viscosity and high gelation properties in relation to PVC. At the same time, its ability to reduce the glass transition temperature and elasticize the polymer in the glassy and rubbery state is somewhat lower than that of phthalate plasticizers. PVC samples plasticized with DBP have the highest resistance to light-thermal aging.

Details

ISSN :
18207421 and 03525139
Volume :
87
Database :
OpenAIRE
Journal :
Journal of the Serbian Chemical Society
Accession number :
edsair.doi...........149f807824a335f2413bf1d4abfae6f1
Full Text :
https://doi.org/10.2298/jsc210817093t