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Localized and Delocalized Electrons in Room-Temperature Stable Electride [Ca24Al28O64]4+(O2-)2-x(e-)2x: Analysis of Optical Reflectance Spectra
- Source :
- The Journal of Physical Chemistry C. 112:4753-4760
- Publication Year :
- 2008
- Publisher :
- American Chemical Society (ACS), 2008.
-
Abstract
- [Ca24Al28O64]4+(O2-)2-x(e-)2x (0 ≤ x ≤ 2, C12A7:e-) crystal shows a metal−insulator transition at x ∼ 1. Varied concentrations of electrons (Ne) are introduced in the subnanometer-sized crystallogr...
Details
- ISSN :
- 19327455 and 19327447
- Volume :
- 112
- Database :
- OpenAIRE
- Journal :
- The Journal of Physical Chemistry C
- Accession number :
- edsair.doi...........140d651590169199833f788577b55ea5
- Full Text :
- https://doi.org/10.1021/jp711631j