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Synthesis, structure and spectroscopic properties of CuL(MeOH), H2L = (E)-N 1-(2-((2-aminocyclohexydiimino)(phenyl)methyl)-4-chlorophenyl)-N 2-(2-benzyl-4-chlorophenyl)oxalamide
- Source :
- Journal of Coordination Chemistry. 58:857-862
- Publication Year :
- 2005
- Publisher :
- Informa UK Limited, 2005.
-
Abstract
- A new kind of copper(II) complex, CuL(MeOH) (H2L = (E)-N 1-(2-((2-aminocyclohexydiimino)(phenyl)methyl)-4-chlorophenyl)-N 2-(2-benzyl-4-chlorophenyl)oxalamide) has been synthesized and its structure determined by single-crystal X-ray methods. Copper(II) ion is five-coordinate, bonding to four nitrogen atoms from H2L and one oxygen atom from MeOH. Hydrogen bonds in the crystal result in the formation of a one-dimensional structure. EPR spectra are discussed. Computer simulation gave g|| = 2.200, g⊥ = 2.002. On the basis of the synthesis and the crystal structure, the mechanism of the metal template reaction involved in the formation of the complex was verified.
Details
- ISSN :
- 10290389 and 00958972
- Volume :
- 58
- Database :
- OpenAIRE
- Journal :
- Journal of Coordination Chemistry
- Accession number :
- edsair.doi...........13dc0a28d38ad75fbe531040c1e81918