Back to Search Start Over

Catalytic H/D Exchange between Organic Compounds and D2O with TpRu(PPh3)(CH3CN)H (Tp = hydro(trispyrazolyl)borate). Reaction of TpRu(PPh3)(CH3CN)H with Water to Form Acetamido Complex TpRu(PPh3)(H2O)(NHC(O)CH3)

Authors :
Wenxu Zheng
Chung Wing Leung
Siu-Man Ng
Zhong Yuan Zhou
Chak Po Lau
Dexian Wang
Chi Hung Yeung
Zhenyang Lin
Source :
Organometallics. 26:1924-1933
Publication Year :
2007
Publisher :
American Chemical Society (ACS), 2007.

Abstract

Deuteration of organic molecules using D2O as the deuterium source is affected with catalytic systems based on the ruthenium solvento hydride complex TpRu(PPh3)(CH3CN)H. The deuteration reactions c...

Details

ISSN :
15206041 and 02767333
Volume :
26
Database :
OpenAIRE
Journal :
Organometallics
Accession number :
edsair.doi...........1287e18bdb30ff2991df8d743c658fe2
Full Text :
https://doi.org/10.1021/om061045x