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PALLADIUM-CATALYZED CARBONYLATIVE COUPLING OF ORGANOLEAD COMPOUNDS: SYNTHESIS OF SYMMETRICAL KETONES

Authors :
Suk-Ku Kang
Hyung-Chul Ryu
Sang-Chul Choi
Source :
Synthetic Communications. 31:1035-1039
Publication Year :
2001
Publisher :
Informa UK Limited, 2001.

Abstract

Organolead acetates can be carbonylated in the presence of Pd2(dba)3·CHCl3 (5 mol%) and NaOMe (5 equiv.) in CH3CN under atmospheric pressure of carbon monoxide at room temperature to afford symmetrical ketones.

Subjects

Subjects :
Coupling (electronics)
chemistry.chemical_compound
Atmospheric pressure
chemistry
Organic Chemistry
chemistry.chemical_element
Photochemistry
Catalysis
Palladium
Carbon monoxide

Details

ISSN :
15322432 and 00397911
Volume :
31
Database :
OpenAIRE
Journal :
Synthetic Communications
Accession number :
edsair.doi...........1225bde84e6167ca7706debc720b586c
Full Text :
https://doi.org/10.1081/scc-100103533
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