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Formation of completely miscible solid-solution Gd5(Si1−xGex)4 induced by ferromagnetic exchange interaction

Authors :
H.F. Yang
Junjun Liang
G.H. Rao
Q.L. Liu
Source :
Journal of Alloys and Compounds. 325:50-53
Publication Year :
2001
Publisher :
Elsevier BV, 2001.

Abstract

The crystal structure and magnetic properties of Gd-5(Si1-xGex)(4) compounds (0 less than or equal to x less than or equal to 1.0) are investigated by means of temperature dependent X-ray powder diffraction and magnetic measurements. A crystallographic and magnetic phase diagram of the pseudobinary system Gd5Si4-Gd5Ge4 is constructed. An intriguing observation is that Gd-5(Si1-xGex)(4) alloys form a completely miscible solid-solution at low temperature (< T-C), crystallizing in the Gd5Si4-type structure as indicated by the well-defined linear dependence of lattice parameters on germanium concentration x, and decomposing into three partially miscible solid-solutions above the Curie temperature, i.e. Gd5Si4 based (x < 0.5), Gd5Ge4 based (x greater than or equal to 0.8) and Gd5Si2Ge2 based (0.5 less than or equal to x < 0.8) solid-solutions, This unusual feature can be understood by taking into account competing effects of ferromagnetic exchange interaction and lattice strain in the solid-solution. (C) 2001 Elsevier Science B.V. All rights reserved.

Details

ISSN :
09258388
Volume :
325
Database :
OpenAIRE
Journal :
Journal of Alloys and Compounds
Accession number :
edsair.doi...........11cc211d27245b6173957ee16d841f42
Full Text :
https://doi.org/10.1016/s0925-8388(01)01392-5