Back to Search Start Over

Synthesis and reaction of N-methyl-N-tosylpyrrolidinium perchlorate, a selective tosylating reagent

Authors :
Takeshi Oishi
Kazuyuki Kamata
Yoshio Ban
Sadako Kosuda
Source :
Journal of the Chemical Society, Chemical Communications. :1148
Publication Year :
1972
Publisher :
Royal Society of Chemistry (RSC), 1972.

Abstract

Reaction of N-methylpyrrolidine and tosyl chloride in the presence of AgClO4 afforded N-methyl-N-tosylpyrrolidinium perchlorate (II) as a stable, crystalline salt, which can be used for the selective tosylation of an amino-group in the presence of a hydroxy-group.

Details

ISSN :
00224936
Database :
OpenAIRE
Journal :
Journal of the Chemical Society, Chemical Communications
Accession number :
edsair.doi...........1183c1e30a1fd18483d1d7ff15e853d7
Full Text :
https://doi.org/10.1039/c39720001148