Chemically pumped O2(a-X) laser

A theoretical and experimental study was conducted aimed at achieving laser oscillation in the (a-X) electronic transition of oxygen molecules. Although this transition is highly forbidden by rigorous selection rules, it may nevertheless concede stimulated emission, if the population inversion is high enough. The idea is based on a recently developed apparatus, namely, a porous pipe type high-pressure chemical singlet oxygen generator. A numerical model which describes the characteristics of this generator was developed to estimate the population inversion and small-signal gain achievable in a laser cavity using this source. The calculations showed that the small-signal gain ought to be sufficient to achieve laser oscillation. Preliminary experiments were conducted, but lasing was not yet observed. It is shown that the scattering losses caused by water droplet aerosols are mainly responsible for preventing our system from laser oscillation.