Back to Search Start Over

[Untitled]

Authors :
Donald A. Palmer
Patience C. Ho
Hugo Bianchi
Robert H. Wood
Source :
Journal of Solution Chemistry. 29:217-235
Publication Year :
2000
Publisher :
Springer Science and Business Media LLC, 2000.

Abstract

A flow-through electrical conductance cell was assembled in order to measuremolar conductances of dilute aqueous electrolytes with a high degree of accuracyat high temperatures and pressures. The design of the cell is based on the conceptdeveloped at the University of Delaware and built in 1995, with modificationsthat will allow the cell to operate at much higher temperatures (to 600°C) andpressures (to 300 MPa). At present, the cell has been tested successfully bymeasuring aqueous (10−4-10−3 mol-kg−1) solutions of LiCl, NaCl, and KCl attemperatures 25–410°C and pressures 9.8–33 MPa. The results are in goodagreement with reported values, including those measured with the Delawareflow-through cell. These new results are also complementary to our previousresults, which were measured with a static high-pressure cell. Measurements attemperatures near the critical point of water (374°C, 22.1 MPa) require the useof lower solution concentrations that were unachievable in the past with thestatic cell.

Details

ISSN :
00959782
Volume :
29
Database :
OpenAIRE
Journal :
Journal of Solution Chemistry
Accession number :
edsair.doi...........10351e1c9ed92758e8a591223bad7fe6
Full Text :
https://doi.org/10.1023/a:1005146332605